De-ionised water is not the same as distilled water, but in my experince either is good enough for engine cooling.
Just don't put that cr@p that they have in London, or other similarly "hard" water into your engine!
I use the condensate out of my dehumidifier, there's plenty of that here at this time of year!
I recall you can buy deionised water in Tesco/asda (used in steam irons), probably as cheap as anywhere?