Hi, did you ever get to the bottom of this? I have a mk5 2.0 tfsi with the same problems. The car has no fault codes, and has had various parts changed; PVC, spark plugs, temp sensor and fuel filter changed, still no joy.
If the car has been left for a few hours it hesitates when pulling off like it's getting no fuel. This is very brief and after runs perfectly. I have been told that this is 'choke mode' and this is supposed to happen?! I'm lost as never heard of this or had this issue before.