Mk7 hubs are based from a completely different platform with is the MQB where the Mk5, Mk6, Rocco, jetta, passat etc etc is based on the PQ.
I've personally drive with Passat B6 front hubs, with Passat B6 wishbones and then also Passat B6 rear hubs.
When you look in ETKA same partnumbers is showing for the alloy parts from Cupra, Passat, S3 - the TT is different, can work but then you also would need track rods from TT. which is more work and not much gain.
Passat setup front widens about 6mm each front wheel
Passat setup rear widens about 12mm each rear wheel - I drive 18'' 225/40 on ET48 and rear tyres stick a few mm out from rear wheel fender.
With all that said….. I've got no clue if the MK7 front or rear hubs will fit the your mk5. Rear calipers are different, but front calipers can be swapped as you like. I've personally drive with 4pot Audi TTS front on 340mm disc with mk6 R 310mm rear.